Engr. Edgar Clyde R. Lopez, Ph.D. Chemical Engineering candidate, presented his research on CD-MOF composite beads at the 8th International Conference on Applied Engineering, Materials and Mechanics (ICAEMM 2023), July 14-16, 2023, at Fraser Place Hotel, Seoul, South Korea.
Textile dyes are notorious for producing highly-colored effluents with high organic loadings, posing significant environmental concerns when discharged into the environment. These dyes not only devalue water but also disrupt aquatic photosynthesis and may even be toxic to humans and other organisms. To address this issue, the need to remove textile dyes from wastewater before disposal is of paramount importance. Among the various methods available for textile dye removal, adsorption has emerged as the best technology due to its simplicity in operation. It involves the migration of textile dyes from wastewater to active sites in an adsorbent material, driven by the concentration gradient between the solid-liquid interface. However, traditional adsorbents like activated carbon and zeolites have limited surface areas, resulting in low sorption capacities.
In recent years, metal-organic frameworks (MOFs) have emerged as outstanding candidates for adsorbent materials due to their ultrahigh surface area and porosity. MOFs are composed of metal ions coordinated with organic ligands, offering the advantage of easy fine-tuning through functionalization to enhance their sorption capacity further. Among the various MOFs, cyclodextrin-based MOFs (CD-MOFs) have gained popularity due to their sustainable synthesis from green precursors.
CD-MOFs have found numerous applications due to their ability to form host-guest complexes. However, their applicability in aqueous environments has been limited by their moisture instability.
To overcome this challenge, researchers have explored various approaches to endow CD-MOFs with moisture stability. One of the most promising solutions is to use polyacrylonitrile (PAN) as a hydrophobic polymeric shield for CD-MOFs, making them suitable for wastewater treatment applications. Additionally, polyvinylpyrrolidone (PVP) is introduced as a functionalizing agent to compensate for the reduced sorption capacity of CD-MOFs when encapsulated in a hydrophobic matrix.
The PAN/PVP/CD-MOF composite beads show great promise as an effective and sustainable adsorbent for textile dye removal from wastewater. The innovative approach of using PAN as a hydrophobic shield and PVP as a functionalizing agent has overcome the moisture instability issue of CD-MOFs. With their outstanding sorption capacities for methylene blue and congo red, the composite beads offer an efficient solution for addressing the environmental impact of textile dyes on water resources. This breakthrough can potentially revolutionize wastewater treatment methods and contribute to a cleaner and healthier environment.